e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Synthesis of 7, 9-didecarboxymethoxatin (4, 5-dihydro-4, 5-dioxo-1H-pyrrolo [2, 3-f] quinoline-2-carboxylic acid) and comparison of its chemical properties with those …
PR Sleath, JB Noar, GA Eberlein…
Index: Sleath,P.R.; Noar,J.B.; Eberlein,G.A. Journal of the American Chemical Society, 1985 , vol. 107, p. 3328
Abstract: The synthesis of 4, 5-dihydro-4, 5-dioxo-1 H-pyrrolo [2, 3-flquinoline-2-carboxylic acid (7, 9-didecarboxymethoxatin, 7,,) and its ester (60x) are described and their acid-base properties, electrochemistry, and chemical properties are compared to the cofactor Methoxatin, as well as to those of other o-quinones. The two-electron redox potentials of 6,, and 7,, are shown to be ca. 110 mV less than those of the penanthroline-5, 6-quinones but ...