Derivatives of sym-triazine. 1. Synthesis and conversions of quaternary methylammonium salts of 2-chloro-4, 6-disubstituted 1, 3, 5-triazines in nucleophilic …

AA Chesniuk, SN Mikhailichenko, VS Zavodnov…

Index: Chesniuk; Mikhailichenko; Zavodnov; Zaplishny Chemistry of Heterocyclic Compounds, 2002 , vol. 38, # 2 p. 177 - 182

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Citation Number: 7

Abstract

Abstract New quaternary ammonium salts of monochloro-4, 6-disubstituted 1, 3, 5-triazines have been obtained. These compounds are convenient synthons for the synthesis of new cyano, alkoxy, and other derivatives of sym-triazine. Some conversions of the synthesized salts have been studied. An elimination-isomerization reaction of the sym-triazine ring into a 2-oxo-1, 2-dihydro-sym-triazine ring was discovered.