A straightforward synthesis of symmetrical polyendiynes by dimerization reactions of silyl derivatives

F Babudri, V Fiandanese, G Marchese…

Index: Babudri, Francesco; Fiandanese, Vito; Marchese, Giuseppe; Punzi, Angela Journal of Organometallic Chemistry, 1998 , vol. 566, # 1-2 p. 251 - 257

Full Text: HTML

Citation Number: 13

Abstract

A straightforward synthesis of polyendiynes is described. The method is based upon a simple dimerization reaction of silylated enynes in the presence of copper salts. A variety of polyunsaturated compounds have been obtained in high yields and with high retention of configuration.

~77%

An Unprecedented Iridium (III) Catalyst for Stereoselective ...

[Ciclosi, Marco; Estevan, Francisco; Lahuerta, Pascual; Passarelli, Vincenzo; Perez-Prieto, Julia; Sanau, Mercedes Advanced Synthesis and Catalysis, 2008 , vol. 350, # 2 p. 234 - 236]

Hydroalumination of 1-(trimethylsilyl-1, 3-diynes). Synthese...

[Miller, Joseph A.; Zweifel, George Journal of the American Chemical Society, 1983 , vol. 105, # 5 p. 1383 - 1384]

Highly diastereoselective synthesis of (E)-1-trimethylsilyl-...

[Andreini, Bianca Patrizia; Carpita, Adriano; Rossi, Renzo Tetrahedron Letters, 1988 , vol. 29, # 18 p. 2239 - 2242]

Palladium-catalyzed diastereoselective syntheses of (E)-1-tr...

[Andreini, Bianca Patrizia; Carpita, Adriano; Rossi, Renzo; Scamuzzi, Barbara Tetrahedron, 1989 , vol. 45, # 17 p. 5621 - 5640]