Palladium-catalyzed cyclization of. omega.-olefinic tosamides. Synthesis of nonaromatic nitrogen heterocycles

LS Hegedus, JM McKearin

Index: Hegedus, Louis S.; McKearin, James M. Journal of the American Chemical Society, 1982 , vol. 104, # 9 p. 2444 - 2451

Full Text: HTML

Citation Number: 221

Abstract

Palladium-Catalyzed Cyclization of o-Olefinic Tosamides. ... Louis S. Hegedus* and James M. McKearin ... Contribution from the Department of Chemistry, Colorado State University, Fort Collins, Colorado 80.523. Received September 9, 1981 ... Abstract: The cyclization of aliphatic amino olefins to nonaromatic nitrogen heterocycles has been accomplished by conversion of the amine to the corresponding p-toluenesulfonamide, followed by Pd(I1)-catalyzed ...