e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Multistep electron transfer in palladium-catalyzed aerobic oxidations via a metal macrocycle quinone system
JE Baeckvall, RB Hopkins, H Grennberg…
Index: Baeckvall, Jan-E.; Hopkins, R. Bruce; Grennberg, Helena; Mader, Mary M.; Awasthi, Alok K. Journal of the American Chemical Society, 1990 , vol. 112, # 13 p. 5160 - 5166
Abstract: Selective palladium-catalyzed aerobic conditions of olefins and conjugated dienes with the aid of a metal macrocycle-quinone system have been developed. This involves a multistep electron transfer with three catalysts (Pd (OAc) 2, hydroquinone, metal macrocycle). The triple catalytic system was applied to (i) 1, 4-oxidation of conjugated dienes (1, 4-diacetoxylation and 1, 4-dialkoxylation),(ii) oxidation of terminal olefins to ...
