The Journal of Organic Chemistry

Studies on paraionic compounds. Anhydro-1-hydroxy-3-oxopyrazolo [1, 2-a] pyrazolium hydroxides. Formation and stability of a novel series of 4n. pi. heterocyclic …

G Zvilichovsky, M David

Index: Zvilichovsky, Gury; David, Mordechai Journal of Organic Chemistry, 1982 , vol. 47, # 2 p. 295 - 300

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Citation Number: 20

Abstract

Different substituted anhydro-l-hydroxy-3-oxopyrazolo [1, 2-a] pyrazolium hydroxides were prepared by the reaction of l, 3-dicarbonyl compounds with derivatives of 4-phenyl-3, 5- dihydroxypyrazole. These diazapentalene derivatives belong to a new series of 4n? r cyclic betaines which are named" paraionic" heterocycles. The effects of substituents on the stability of both the anionic and the cationic rings were kinetically studied. Selective ...