Fluoroalkenyl, fluoroalkynyl and fluoroalkyl phosphines

KK Banger, AK Brisdon, CJ Herbert, HA Ghaba…

Index: Banger, Kulbinder K.; Brisdon, Alan K.; Herbert, Christopher J.; Ghaba, Hana Ali; Tidmarsh, Ian S. Journal of Fluorine Chemistry, 2009 , vol. 130, # 12 p. 1117 - 1129

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Citation Number: 13

Abstract

A review of the methods available for the preparation of monodentate P (III) compounds containing fluoroalkenyl, fluoroalkynyl and fluoroalkyl groups is given. The synthesis, properties and coordination chemistry of some fluoroalkenyl-and fluoroalkynyl-containing phosphines derived from HFC-134a (CF3CH2F) and HFC-245fa (CF3CH2CH2F) is summarised. The development of the reaction between trimethylsilyl-containing ...