Chemical communications

The synthesis of tris (perfluoroalkyl) phosphines

MB Murphy-Jolly, LC Lewis, AJM Caffyn

Index: Murphy-Jolly, Makeba B.; Lewis, Lesley C.; Caffyn, Andrew J. M. Chemical Communications, 2005 , # 35 p. 4479 - 4480

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Citation Number: 23

Abstract

Tris (perfluoroalkyl) phosphines, of interest as tunable alternatives to the carbon monoxide ligand, can be synthesised by the nucleophile mediated reaction of perfluoroalkyltrimethylsilanes with triphenylphosphite; the method can be extended to diphosphines.