e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Synthesis of 3??O?螃漫?d??Glucopyranosyl??(3 R)??hydroxybutanolide (Kinsenoside) and 3??O?螃漫?d??Glucopyranosyl??(3 S)??hydroxybutanolide (Goodyeroside A)
The first synthesis of 3??O?螃漫?d??glucopyranosyl??(3 R)??hydroxybutanolide (Kinsenoside) and 3??O?螃漫?d??glucopyranosyl??(3 S)??hydroxybutanolide (Goodyeroside A) is described. The diastereomers of the aglycon in 2??O?螃漫?d??gulucopyranosyl??1, 2, 4??butanetriol derivatives, which were separable precursors of Kinsenoside and Goodyeroside A, were synthesized from optically nonactive 1, 2, 4??butanetriol and α??d??glucopyranosyl trichloroacetimidate in ...