Chemistry of acetylenic ethers XLII: A simplified method for the preparation of acetylenic thioethers; a number of new reactions of these compounds

HJ Boonstra, JF Arens

Index: Boonstra,H.J.; Arens,J.F. Recueil des Travaux Chimiques des Pays-Bas, 1960 , vol. 79, p. 866 - 887

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Citation Number: 28

Abstract

H. J. BOONSTRA and J. F. ARENS ... (Laboratory of Organic Chemistry of the State University, Groningen, The Netherlands) ... Cis ethenylene- 1 ,Zbis-thioethers RSCH = CHSR can easily be prepared in liquid ammonia by treating cis or tvans 1,Zdichloro- ethylene with sodium amide and thiol. From these compounds acetylene thioethers HC =CSR can be ob- tained by means of sodium amide in liquid ammonia, followed by treatment with one mole of alkyl ...