An ethylene and terminal olefin equivalent in [4+ 2]. pi. cycloadditions. General synthetic application of phenyl vinyl sulfone to the construction of functionalized six- …

RVC Carr, LA Paquette

Index: Carr, Richard V. C.; Paquette, Leo A. Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 853 - 855

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Citation Number: 68

Abstract

The widespread use of the Diels-Alder reaction in synthetic organic methodology stems in large part from the frequent need to elaborate six-membered rings and the customarily high efficiency of such cycloadditions. A long-standing restriction to the universal application of this chemistry materializes when the diene and dienophile have no 7r-donor-acceptor complementarity. This phenomenon is witnessed perhaps most acutely in the case of ...

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