The Catalyzed Desulfinylative Allylation of Carbonyl Compounds with Alk??2??enesulfonyl Chlorides and Silyl Alk??2??enesulfinates

…, D Marković, S Laclef, P Vogel

Index: Volla, Chandra M. R.; Markovic, Dean; Laclef, Sylvain; Vogel, Pierre Chemistry - A European Journal, 2010 , vol. 16, # 30 p. 8984 - 8988

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Citation Number: 10

Abstract

Carbon–carbon cross-coupling reactions are very important in the areas of material science and medicinal chemistry.[1] Transition-metal-catalyzed cross-coupling of organometallic reagents (nucleophiles) with halides or triflates (electrophiles) constitutes one of the most powerful methods for constructing CÀC bonds.[2] Arene-and alkanesulfonyl chlorides are inexpensive and readily available compounds. We have shown that Stille, carbonylative ...