Journal of the American Chemical Society

Reaction of ozonide with antimony pentachloride or chlorosulfuric acid. Participation of antimony pentachloride-complexed or protonated carbonyl oxide

M Miura, M Nojima

Index: Miura,M.; Nojima,M. Journal of the American Chemical Society, 1980 , vol. 102, p. 288

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Citation Number: 17

Abstract

Abstract: The reactions of 1 1 kinds of 1, 2, 4-trioxolanes (ozonides) with SbCIS or CIS03H in methylene chloride have been investigated. Depending on the substituents, the reaction paths seem to vary. We have proposed the mechanism that heterolytic fission of the C-0 bond of the peroxide bridge affords 3, 6-dialkyl-1, 2, 4, 5-tetroxane and/or 1, 4-dialkyl-2, 3, 5, 6, 1 I-pentaoxabicyclo [5.3. Ilundecane. The reaction of methylcyclopentene ozonide with ...