2-Cyano-. DELTA. 3-piperideines. 12. Stereochemistry of formation of N-benzyl-2-cyano-. DELTA. 3-piperideines and facile isomerization on alumina to 2-cyano-. …

M Bonin, JR Romero, DS Grierson…

Index: Journal of Organic Chemistry, , vol. 49, # 13 p. 2392 - 2400

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Citation Number: 45

Abstract

... di- hydropyridinium salts 2 (Scheme I). These compounds are potentially powerful synthons for the preparation of functionalized piperidines as one can envisage successive control over three of the ring carbon centers (C-2,3,4). However, the chemistry of this ... J. Org. Chem., Vol. ...