Tetrahedron letters

Pd 2+-promoted cyclization in tetracyclic diterpene synthesis highly diastereoselective formal total synthesis of (±)-stemodin

M Toyota, T Seishi, K Fukumoto

Index: Toyota, Masahiro; Seishi, Takashi; Fukumoto, Keiichiro Tetrahedron Letters, 1993 , vol. 34, # 37 p. 5947 - 5950

Full Text: HTML

Citation Number: 17

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Intramolecular Diels-Alder reaction of the triene 5 and Pd 2+ -promoted cyclization reaction of the olefinic silyl enol ether of 10 have been utilized as the key steps for a conceptually new, highly diastereocontrolled formal total synthesis of (±) stemodin (1).