Copper??Catalyzed Asymmetric Conjugate Addition of Trialkylaluminium Reagents to Trisubstituted Enones: Construction of Chiral Quaternary Centers

M Vuagnoux??d'Augustin…

Index: Vuagnoux-D'Augustin, Magali; Alexakis, Alexandre Chemistry - A European Journal, 2007 , vol. 13, # 34 p. 9647 - 9662

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Citation Number: 113

Abstract

Abstract Me 3 Al, Et 3 Al, and vinylalane species undergo enantioselective conjugate addition to a wide range of 2-or 3-substituted enones (cyclopent-2-enones, cyclohex-2- enones, 3-methyl cyclohept-2-enone) in the presence of catalytic amount of copper salt ( ...

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