Journal of the American Chemical Society

Proton transfer from carbon acids to carbanions. 1. Reactions of various carbon acids with the anions of substituted benzylmalononitriles in 90% Me2SO-10% water. …

CF Bernasconi, JX Ni

Index: Bernasconi, Claude F.; Ni, Jiu Xiang Journal of the American Chemical Society, 1993 , vol. 115, # 12 p. 5060 - 5066

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Citation Number: 22

Abstract

Abstract: A kinetic study of the reversible deprotonation of 9-cyanofluorene (2), 1, 3- indandione (3), 4-nitrophenylacetonitrile (4),(3-nitropheny1) nitromethane (9, and (4- nitropheny1) nitromethane (6) by the anions of substituted benzylmalononitrile (1-X-) in 90% Me2SO-10% water (v/v) at 20 OC is reported. Intrinsic rate constants and intrinsic barriers of these reactions have been determined by extrapolation or interpolation of Brransted plots ...

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