New reaction of glycidols with oxalyl chloride and phosgene—an approach to cyclic esters

…, AV Pashagin, EI Strunskaya, AT Gubaydullin…

Index: Bredikhin; Pashagin; Strunskaya; Gubaydullin; Litvinov; Bredikhina Russian Chemical Bulletin, 1999 , vol. 48, # 11 p. 2086 - 2090

Full Text: HTML

Citation Number: 1

Abstract

Abstract 2, 3-Epoxy alcohols (glycidols) react with carboxylic acid dichlorides to form cyclic esters of 3-chloro-1, 2-diols. The reaction proceeds with complete retention of the configuration of the C (2) atom of the initial glycidol and with predominant (but not complete) inversion of the configuration of the C (3) atom in the final heterocycle.

~75%

~66%

Converting wastes into added value products: from glycerol t...

[Dibenedetto, Angela; Angelini, Antonella; Aresta, Michele; Ethiraj, Jayashree; Fragale, Carlo; Nocito, Francesco Tetrahedron, 2011 , vol. 67, # 6 p. 1308 - 1313]

Pd/C: an efficient and heterogeneous protocol for oxidative ...

[Chavan, Sujit P.; Bhanage, Bhalchandra M. Tetrahedron Letters, 2014 , vol. 55, # 6 p. 1199 - 1202]

Catalytic activity of metal organic framework Cu 3 (BTC) 2 i...

[MacIas, Eugenia E.; Ratnasamy, Paul; Carreon, Moises A. Catalysis Today, 2012 , vol. 198, # 1 p. 215 - 218]

One-component catalysts for cyclic carbonate synthesis

[Melendez, Jaisiel; North, Michael; Villuendas, Pedro Chemical Communications, 2009 , # 18 p. 2577 - 2579]