Tetrahedron

Converting wastes into added value products: from glycerol to glycerol carbonate, glycidol and epichlorohydrin using environmentally friendly synthetic routes

…, A Angelini, M Aresta, J Ethiraj, C Fragale, F Nocito

Index: Dibenedetto, Angela; Angelini, Antonella; Aresta, Michele; Ethiraj, Jayashree; Fragale, Carlo; Nocito, Francesco Tetrahedron, 2011 , vol. 67, # 6 p. 1308 - 1313

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Citation Number: 78

Abstract

Glycerol carbonate, synthesised via a non-phosgene route using glycerol and CO2 or urea in presence of a heterogeneous catalyst, was efficiently converted into a series of derivatives through the functionalization of the–OH moiety, using high yield, high selectivity synthetic routes not affecting the carbonate functionality. So, for example, glycerol carbonate was converted into epichlorohydrin, a product that has a large industrial application, under ...