Trapping Reactive Metal–Carbene Complexes by a Bis??Pocket Porphyrin: X??ray Crystal Structures of Ru CHCO2Et and trans??[Ru (CHR)(CO)] Species and Highly …

QH Deng, J Chen, JS Huang, SSY Chui…

Index: Deng, Qing-Hai; Chen, Jian; Huang, Jie-Sheng; Chui, Stephen Sin-Yin; Zhu, Nianyong; Li, Guang-Yu; Che, Chi-Ming Chemistry - A European Journal, 2009 , vol. 15, # 41 p. 10707 - 10712

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Citation Number: 22

Abstract

The formation of CÀC bonds by a metal-catalyzed reaction of diazo compounds N2CR1R2 with hydrocarbons, via putative metal–carbene intermediates, has a wide spectrum of applications in organic synthesis.[1] Identification of the reactive metal–carbene ...