Reactions of atoms and free radicals in solution. XI. The addition of bromotrichloromethane to olefins

MS Kharasch, O Reinmuth, WH Urry

Index: Kharasch; Reinmuth; Urry Journal of the American Chemical Society, 1947 , vol. 69, p. 1108

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Citation Number: 105

Abstract

(25 9.) was then added, and the mixture was subjected to steam distillation. The oil which distilled was taken up in low-boiling ligroin, the ligroin solution washed with water, and sodium carbonate solution (lo%), and dried over anhydrous sodium sulfate. On distillation, there was obtained an oil (9 g.), bp 90-110" (12 mm.); n Z o ~ 1.4520. This material formed a 2,4-dinitrophenylhydra- zone which melted at 125-126', and did not depress the melting ...