Cohen3 made the interesting discovery that 1-vinylnaphthalene can function as a diene in the Diels-Alder reaction. From the reaction of this hydrocarbon with maleic anhydride in xylene, cis-1, 2, 3, 10a-tetrahydrophenanthrene-1, 2-dicarboxylic anhydride (Ia) was~ btained.~ The product was isomerized to the naphthalenic compound 1, 2, 3, 4- tetrahydrophenanthrene-1, 2-dicarboxylic anhydride (IIa) by treatment with glacial acetic ...