The Reaction of 1-Vinylnaphthalene and 6-Methoxy-1-vinylnaphthalene with Citraconic Anhydride, Fumaric Acid and Mesaconic Acid1

WE Bachmann, LB Scott

Index: Bachmann; Scott Journal of the American Chemical Society, 1948 , vol. 70, p. 1462,1465

Full Text: HTML

Citation Number: 17

Abstract

Cohen3 made the interesting discovery that 1-vinylnaphthalene can function as a diene in the Diels-Alder reaction. From the reaction of this hydrocarbon with maleic anhydride in xylene, cis-1, 2, 3, 10a-tetrahydrophenanthrene-1, 2-dicarboxylic anhydride (Ia) was~ btained.~ The product was isomerized to the naphthalenic compound 1, 2, 3, 4- tetrahydrophenanthrene-1, 2-dicarboxylic anhydride (IIa) by treatment with glacial acetic ...