Reactions of 1-nitrocyclohexene with N, N-binucleophiles

…, LV Lapshina, GA Berkova, VM Berestovitskaya

Index: Efremova; Vakulenko; Lysenko; Bushmarinov; Lapshina; Berkova; Berestovitskaya Russian Journal of General Chemistry, 2010 , vol. 80, # 11 p. 2298 - 2305

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Abstract

Abstract A modification of 1-nitrocyclohexene synthesis is proposed; its reaction with phenylhydrazine and benzoic acid hydrazide is shown to afford monoadducts, and with hydrazine hydrate, bisaduct. With diphenylguanidine occurs heterocyclization to 1-phenyl-2- N-phenylamino-4, 5, 6, 7-tetrahydrobenzimidazole, whose structure is confirmed by the X- ray diffraction data. The analysis performed for this compound of the electron density ...