Iron (II)??Mediated Reductive Cleavage of Disulfide and Diselenide Bonds: Iron (III) Complexes of Mixed O, X, O and O, X (X= S, Se) Donor Ligands

…, D Sheet, T Weyhermüller, P Chaudhuri

Index: Kanti Paine, Tapan; Sheet, Debobrata; Weyhermueller, Thomas; Chaudhuri, Phalguni European Journal of Inorganic Chemistry, 2011 , # 34 p. 5250 - 5257

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Citation Number: 3

Abstract

Abstract The syntheses and characterization of a methoxo-bridged diiron (III) complex,[Fe 2 L Se 2 (μ-OCH 3) 2 (CH 3 OH) 2](1), and three mononuclear iron (III) complexes Bu 4 N [FeL Se 2](2), Bu 4 N [FeL Se′ L Se](3) and Bu 4 N [FeL S′ LS](4)[H 2 L Se= 2, 2′-selenobis (4, 6-di-tert-butylphenol), H 2 LS= 2, 2′-thiobis (4, 6-di-tert-butylphenol), H 2 L Se′= 3, 5-di- tert-butyl-2-hydroxyselenophenol, and H 2 LS′= 3, 5-di-tert-butyl-2-hydroxythiophenol] ...