Bulletin of the Chemical Society of Japan

Iodination of Both Deactivated and Activated Arenes with Sodium Periodate or Sodium Iodate as the Oxidants.

P Lulinski, L Skulski

Index: Lulinski, Piotr; Skulski, Lech Bulletin of the Chemical Society of Japan, 2000 , vol. 73, # 4 p. 951 - 956

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Citation Number: 50

Abstract

Five easy, relatively inexpensive, and environmentally-safe aromatic oxidative iodination procedures are presented; three of them are particularly suitable for deactivated arenes. Nine deactivated arenes, four halobenzenes, benzene, toluene, and N, N-dimethylaniline were reacted upon with the following anhydrous systems: diiodine/NaIO 4 or (in four cases) NaIO 3/acetic anhydride/glacial acetic acid, acidified with varying amounts of concd (98%) ...