The Journal of Organic Chemistry

N-Substitution of 2-methyl-4 (5)-nitro-1H-imidazole: a new, high-yield method for preparation of 4-nitro isomers

AKSB Rao, CG Rao, BB Singh

Index: Rao, A. K. S. Bhujanga; Rao, C. Gundu; Singh, B. B. Journal of Organic Chemistry, 1990 , vol. 55, # 11 p. 3702 - 3704

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Citation Number: 18

Abstract

J. Org. Chem., Vol. 55, No. 11, 1990 3703 example, the chemical shifts of carbon C-5 are about 122 ppm for the 4-nitro isomers and 139 ppm for the 5-nitro isomers, whereas chemical shifts for carbon C-4 are 145 ppm for the 4-nitro and 133 ppm for the corresponding 5-nitro compounds. As can be seen from Table 11, the I3C chemical shift values for 3a-e are in exactly the same range, 122.0-122.7 ppm for the C-5 carbon and ...