An experimental study on the photochemistry and vibrational spectroscopy of three isomers of Cl2O2 isolated in cryogenic matrixes

J Jacobs, M Kronberg, HSP Mueller…

Index: Jacobs, Juergen; Kronberg, Marc; Mueller, Holger S. P.; Willner, Helge Journal of the American Chemical Society, 1994 , vol. 116, # 3 p. 1106 - 1114

Full Text: HTML

Citation Number: 70

Abstract

Abstract: Chloryl chloride, ClC102, isolated in cryogenic matrices is subjected to photolysis, producing chlorine chlorite, ClOClO, which in turn is converted into dichlorine peroxide, ClOOCl. ClOClO is also formed by the reactions C1+ OClO and ClOCl+ 0. The products are identified by means of FTIR spectroscopy using 35/37C1 and la/lsO isotopic shifts, with the aid of vibrational spectra of related molecules and results of ab initio calculations. The ...