Allyl Amination of Phosphinoquinoline Allyl Complexes of Palladium. Influence of the Allyl Hapticity on the Reaction Rate and Regiochemistry

L Canovese, F Visentin, C Santo, G Chessa…

Index: Canovese, Luciano; Visentin, Fabiano; Uguagliati, Paolo; Bianca, Francesca Di; Antonaroli, Simonetta; Crociani, Bruno Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1994 , # 21 p. 3113 - 3118

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Citation Number: 19

Abstract

The ligands 8-diphenylphosphanylquinoline (DPPQ) and 8-diphenylphosphanyl-2- methylquinoline (DPPQ-Me) react with the allyl dimers [Pd (μ-Cl)(η3-C3H5)] 2 and [Pd (μ- Cl)(η3-C3H3Me2)] 2, yielding palladium allyl phosphanyl-quinoline complexes. The allyl