Journal of the American Chemical Society

A rare, low-valent alkylamido complex, a diphenylamido complex, and their reductive elimination of amines by three-coordinate intermediates

MS Driver, JF Hartwig

Index: Journal of the American Chemical Society, , vol. 117, # 16 p. 4708 - 4709

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Citation Number: 132

Abstract

... Our synthetic chemistry is summarized in Scheme 1. The palladium(II) arylamido compound trans-[P(C&)3]2Pd(C&)- [N(C&&] (1) was prepared by reaction of trans-[P(C&I5)3]2- Pd(Ar)I" with KN(C&i)2.l2 Generation of 1 in THF ... 0 1995 American Chemical Society ... SOC., Vol. ...