Inorganic Chemistry

Synthesis, structural characterization, and electrochemistry of [1] Metallocenophane complexes,[Si (alkyl) 2 (C5H4) 2] MCl2, M= Ti, Zr

CS Bajgur, W Tikkanen, JL Petersen

Index: Bajgur, Chandrasekhar S.; Tikkanen, Wayne R.; Petersen, Jeffrey L. Inorganic Chemistry, 1985 , vol. 24, p. 2539 - 2546

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Citation Number: 161

Abstract

A series of modified metallocene dichloride compounds,[SiRz (C5H4) z] MC12 (M= Ti, R= CH3; M= Zr, R= CH3, C2H5, n-C3H7), have been prepared to evaluate the presence of a dialkylsilyl bridge on their electrochemical behavior. The compounds have been characterized by elemental analysis and'H and') C NMR, and the molecular structures of [Si (CH3) Z (C5H4) z! MC1z, M= Ti, Zr, have been determined by X-ray diffraction methods. ...