The Journal of Organic Chemistry

Activation of reducing agents. Sodium hydride-containing complex reducing agents. 16. FeCRACO, a new reagent for the carbonylation of primary, secondary, and …

JJ Brunet, C Sidot, P Caubere

Index: Brunet, Jean-Jacques; Sidot, Christian; Caubere, Paul Journal of Organic Chemistry, 1981 , vol. 46, # 15 p. 3147 - 3149

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Citation Number: 16

Abstract

Reactions performed in 50 mL of DME under CO with the following reactant ratio: RX/NaH/Am-t-ONa/FeCl,= lo/40/20/10 mmol. halide. In all cases. the side products were shown by GLC to be the corresponding alkanes and alkenes. Determined by GLC analysis with internal standards. Isolated yields, based on consumed alkyl Relative percentages based on isolated yields.-(termed FeCRACO). It might be expected that FeCRACO could ...