Reactions of tert-butyl peroxy esters. X. Preparation of dialkyl tert-butyl phosphates from dialkyl tert-butylperoxy phosphates. Dialkyl phosphorochloridates, and dialkyl …

G Sosnovsky, EH Zaret, KD Schmitt

Index: Sosnovsky,G. et al. Journal of Organic Chemistry, 1970 , vol. 35, p. 336 - 340

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Citation Number: 8

Abstract

Dialkyl t-butyl phosphates (1, R= Me, Et, i-Pr) are produced in low yield by the reaction of the corresponding dialkyl t-butylperoxy phosphates (2) with triphenylphosphine (4), and by the reaction of the corresponding dialkyl phosphorochloridites (8) with t-butyl hydroperoxide (7) in the presence of pyridine. Esters 1 (R= Me, Et, n-Pr, i-Pi-, n-Bu, i-Bu, Ph, PhCHB) are produced in high yield by the reaction of the corresponding dialkyl phosphorochloridates ( ...