Photosensitized oxidations of substituted pyrroles: Unanticipated radical-derived oxygenated products

…, GC Vougioukalakis, M Orfanopoulos

Index: Alberti, Mariza N.; Vougioukalakis, Georgios C.; Orfanopoulos, Michael Journal of Organic Chemistry, 2009 , vol. 74, # 19 p. 7274 - 7282

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Citation Number: 25

Abstract

Photooxidation of pyrrole adducts 7− 10 has been investigated in order to establish a general reaction pattern and mechanism for the formation of the resulting oxygenated products. The reactions were performed in several solvents utilizing both type I and type II sensitizers. In most cases, photooxidations gave complex mixture of products. Among these products, 5, 5-or 6, 5-bicyclic lactams (11, 15, and 19), maleimide 12 unsaturated γ- ...