Entropy control of the cross-reaction between carbon-centered and nitroxide radicals

J Sobek, R Martschke, H Fischer

Index: Sobek; Martschke; Fischer Journal of the American Chemical Society, 2001 , vol. 123, # 12 p. 2849 - 2857

Full Text: HTML

Citation Number: 172

Abstract

Absolute rate constants for the cross-coupling reaction of several carbon-centered radicals with various nitroxides and their temperature dependence have been determined in liquids by kinetic absorption spectroscopy. The rate constants range from< 2× 105 M-1 s-1 to 2.3× 109 M-1 s-1 and depend strongly on the structure of the nitroxide and the carbon-centered radical. Grossly, they decrease with increasing rate constant of the cleavage of the ...

 Related Synthetic Route
Ethyl,2-methoxy-1,1-dimethyl-2-oxo- Structure

2887-41-4

Ethyl,2-methoxy...

~%

dimethyl 2,2,3,3-tetramethylbutanedioate Structure

17072-58-1

dimethyl 2,2,3,...

N-tert-Butyl-N-(2-Methyl-1-phenylpropyl)-O-(1-phenylethyl)hydroxylaMine Structure

227000-59-1

N-tert-Butyl-N-...

~%

1-phenyl-eth-1-yl radical Structure

2348-51-8

1-phenyl-eth-1-...

2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide Structure

61015-94-9

2,2,5-Trimethyl...

2,2,5,5-tetramethyl-3-(1-phenylethoxy)-4-diethylphosphono-3-azahexane Structure

224575-62-6

2,2,5,5-tetrame...

~%

1-phenyl-eth-1-yl radical Structure

2348-51-8

1-phenyl-eth-1-...

N/A Structure

188526-94-5

N/A

4-methoxy-benzyl Structure

3494-45-9

4-methoxy-benzyl

~%

Benzene,1,1'-(1,2-ethanediyl)bis[4-methoxy- Structure

1657-55-2

Benzene,1,1'-(1...

1-phenyl-eth-1-yl radical Structure

2348-51-8

1-phenyl-eth-1-...

2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide Structure

61015-94-9

2,2,5-Trimethyl...

~%

N-tert-Butyl-N-(2-Methyl-1-phenylpropyl)-O-(1-phenylethyl)hydroxylaMine Structure

227000-59-1

N-tert-Butyl-N-...

1-chloro-4-methyl-benzene Structure

3327-51-3

1-chloro-4-meth...

~%

Bis(p-chlorophenyl)ethane Structure

5216-35-3

Bis(p-chlorophe...

2,2,6,6-tetramethyl-1-phenylmethoxypiperidine Structure

102261-92-7

2,2,6,6-tetrame...

~%

2,2,6,6-Tetramethylpiperidinooxy Structure

2564-83-2

2,2,6,6-Tetrame...

Benzyl Structure

2154-56-5

Benzyl

N,N-di-t-butyl-O-benzylhydroxylamine Structure

283600-87-3

N,N-di-t-butyl-...

~%

Benzyl Structure

2154-56-5

Benzyl

di-tert-butyl nitroxide Structure

2406-25-9

di-tert-butyl n...

N-tert-butyl-N-(1-diethoxyphosphoryl-2,2-dimethylpropyl)-O-(benzyl)hydroxylamine Structure

224575-61-5

N-tert-butyl-N-...

~%

Benzyl Structure

2154-56-5

Benzyl

N/A Structure

188526-94-5

N/A

1-cyclohexyloxy-2,2,6,6-tetramethylpiperidine Structure

54051-40-0

1-cyclohexyloxy...

~%

2,2,6,6-Tetramethylpiperidinooxy Structure

2564-83-2

2,2,6,6-Tetrame...

cyclohexanyl Structure

3170-58-9

cyclohexanyl

N-tert-Butyl-N-(2-Methyl-1-phenylpropyl)-O-(1-phenylethyl)hydroxylaMine Structure

227000-59-1

N-tert-Butyl-N-...

~%

1-phenyl-eth-1-yl radical Structure

2348-51-8

1-phenyl-eth-1-...

2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide Structure

61015-94-9

2,2,5-Trimethyl...


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved