Properties and reactions of trimethyl phosphite, trimethyl phosphate, triethyl phosphate, and trimethyl phosphorothionate by ion cyclotron resonance spectroscopy

…, TJ McDonnell, JL Beauchamp

Index: Hodges, Ronald V.; McDonnell, T. J.; Beauchamp, J. L. Journal of the American Chemical Society, 1980 , vol. 102, # 4 p. 1327 - 1332

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Citation Number: 39

Abstract

Abstract: The gas-phase ion-molecule reactions occurring in trimethyl phosphite, trimethyl phosphate, triethyl phosphate, and trimethyl phosphorothionate have been investigated by ion cyclotron resonance spectroscopy. Protonated parent ions, tetracoordinated phosphonium ions, and cluster ions are the reaction products observed. The proton affinities of these compounds have been determined to be 222.9, 214.2, 218.7, and 216.6 kcal/mol, ...