Abstract A series of symmetrically and asymmetrically substituted s-triazines was synthesized by condensation of fluorocarbon nitriles (Scheme II, compounds 1a-c) and by cyclodehydration of a fluorocarbon imidoylamidine utilizing a fluorocarbon anhydride (Scheme III, compounds 2a-e). Among the new nitriles prepared for incorporation in these reaction paths were 11-H-4, 9-dioxahexadecylfluoroundecanenitrile (3) and 6-chloro-6-H- ...