Tetrahedron letters

A new, highly efficient synthesis of conjugated nitrocycloalkenes

R Ballini, C Palestini

Index: Ballini, Roberto; Palestini, Corrado Tetrahedron Letters, 1994 , vol. 35, # 31 p. 5731 - 5734

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Citation Number: 23

Abstract

Abstract Sodium borohydride reduction of α-nitrocycloalkanones and successive dehydration of the obtained β-nitroalkanols, by acetylation and dehydroacetylation with basic alumina/DMAP, in refluxing dichloromethane, affords, in one-pot procedure, conjugated nitrocycloalkenes.

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2-nitrocycloheptan-1-one Structure

13154-27-3

2-nitrocyclohep...

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1-nitrocycloheptene Structure

36291-53-9

1-nitrocycloheptene

2-nitrocycloheptanol Structure

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2-nitrocycloheptanol

2-nitrocycloheptan-1-one Structure

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1-nitrocycloheptene Structure

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1-nitrocycloheptene

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2-nitrocycloheptanol

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1-nitrocycloheptene Structure

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1-nitrocycloheptene

2-NITROCYCLOHEXANONE Structure

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2-NITROCYCLOHEXANONE

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1-nitrocyclohex-1-ene Structure

2562-37-0

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2-NITROCYCLOHEXANONE Structure

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2-NITROCYCLOHEXANONE

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1-nitrocyclohex-1-ene Structure

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2-nitrocyclohexanol Structure

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2-nitrocyclohexanol

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1-nitrocyclohex-1-ene Structure

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88157-67-9

2-nitrocyclooct...

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