Chemistry of α??diazosulfones: Part IV. The preparation of N??(arylsulfonylmethyl) urethanes and N??(alkylsulfonylmethyl) urethanes

AM Van Leusen, J Strating

Index: van Leusen,A.M.; Strating,J. Recueil des Travaux Chimiques des Pays-Bas, 1965 , vol. 84, p. 140 - 150

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Citation Number: 6

Abstract

Abstract In the synthesis of α-diazosulfones (subsequent paper 2) the N-(sulfonylmethyl) urethanes, RSO 2 CH 2 NHCO 2 C 2 H 5, are important intermediates. They have been prepared by means of a Curtius rearrangement of sulfonylacetazides, RSO 2 CH 2 CON 3, which in turn have been obtained from the corresponding esters via the hydrazides.