Chemistry Letters

SYNTHESIS OF 2, 6-DIACETYL-4-C (β-D-GLUCOPYRANOSYL)-4-HYDROXYCYCLOHEXANE-1, 3, 5-TRIONE AND ITS ACID HYDROLYSIS

H Obara, Y Matsui, S Namai, Y Machida

Index: Obara, Heitaro,; Matsui, Yuzo; Namai, Sozo; Machida, Yoshihisa Chemistry Letters, 1984 , p. 1397 - 1398

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Citation Number: 3

Abstract

2, 6-Diacetyl-4-C-(β-D-glucopyranosyl)-4-hydroxycyclohexane-1, 3, 5-trione was obtained by the deacetylation of 2, 6-diacetyl-4-C-(2, 3, 4, 6-tetra-O-acetyl-β-D-glucopyranosyl)-4- hydroxycyclohexane-1, 3, 5-trione which prepared by the C-glucosylation of 2, 6-diacetyl-1, 3, 4, 5-benzenetetrol with 2, 3, 4, 6-tetra-O-acetyl-α-D-glucopyranosyl bromide. The acid hydrolysis of this new C-glucoside was investigated.