Tetrahedron letters

Manganese (III)-based oxidative free-radical reaction of α-allyl-β-keto ester with molecular oxygen

T Ohshima, M Sodeoka, M Shibasaki

Index: Ohshima, Takashi; Sodeoka, Mikiko; Shibasaki, Masakatsu Tetrahedron Letters, 1993 , vol. 34, # 52 p. 8509 - 8512

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Citation Number: 19

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Oxidative reactions of α-allyl-β-keto esters 5 with Mn(OAc) 3 ·2H 2 O give the δ-hydroxy-β-,γ-unsaturated -α-keto esters 6 in good yields. The mechanism of this reaction is discussed. ... Oxidative reactions of α-allyl-β-keto esters with Mn(OAc) 3 ·2H 2 O give the δ-hydroxy-β,γ-unsaturated-α-keto ...