Addition of primary alcohols to 3-chlorononafluoro-1, 5-hexadiene and perfluoro-1, 3, 5-hexatriene

V Dědek, I Linhart, M Kováč

Index: Dedek, Vaclav; Linhart, Igor; Kovac, Milan Collection of Czechoslovak Chemical Communications, 1985 , vol. 50, # 8 p. 1714 - 1726

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Citation Number: 5

Abstract

Abstract Sodium alkoxide-catalyzed addition of methanol, ethanol and propanol to 3- chlorononafluoro-1, 5-hexadiene (I) proceeds at temperatures-35 C to 8 C with allyl rearrangement, affording 1, 6-dialkoxy-1, 1, 2, 3, 4, 4, 5, 6, 6-octafluoro-2, 4-hexadiene (V) as the principal product, along with 1, 6-dialkoxy-1, 2, 3, 3, 4, 5, 6, 6-octafluoro-1, 5-diene (VI) and trans-1, 6-dialkoxy-1, 1, 2, 3, 4, 4, 5, 6, 6-nonafluoro-2-hexene (VII). The ethers Va ...