Improved synthesis of 1-(azidomethyl)-3, 5-bis-(trifluoromethyl) benzene: development of batch and microflow azide processes

ME Kopach, MM Murray, TM Braden…

Index: Jeff Thrasher; Hembre, Erik J.; Gardinier, Kevin M.; Savin, Kenneth A.; Hong, Jian Eric; Jungheim, Louis N. Heterocycles, 2006 , vol. 67, # 2 p. 543 - 547

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Citation Number: 58

Abstract

... of HN 3 . The recommended airborne limits for hydrazoic acid and sodium azide are 0.11 ppm and 0.3 g/m 3 , respectively ... ARC data reveal that azide 1 decomposes at 157 °C with an energy output of 586 J/g over a 10-min ... water (vol), temp (°C), time (h), % azide 1, solids (Y or N) ...