Coordination networks of Ag (I) and N, N′-bis (3-pyridinecarboxamide)-1, 6-hexane: structures and anion exchange

S Muthu, JHK Yip, JJ Vittal

Index: Muthu, Sebastian; Yip, John H.K.; Vittal, Jagadese J. Journal of the Chemical Society. Dalton Transactions, 2002 , # 24 p. 4561 - 4568

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Citation Number: 161

Abstract

A bidentate ligand N, N′-bis (3-pyridinecarboxamide)-1, 6-hexane (L) and its silver complexes have been synthesized and characterized by single crystal X-ray diffraction. Reaction of AgClO4 and L in H2O/EtOH gives rise to a coordination polymer [Ag2L3OH][ClO4]· 2.5 H2O. The X-ray crystal structure of the compound shows honeycomb- like networks in which four-coordinated Ag ions are linked to three-coordinated Ag ions ...