Green Chemistry

Palladium-guanidine complex immobilized on SBA-16: a highly active and recyclable catalyst for Suzuki coupling and alcohol oxidation

H Yang, X Han, Z Ma, R Wang, J Liu, X Ji

Index: Yang, Hengquan; Han, Xiaojing; Ma, Zhancheng; Wang, Runqin; Liu, Jing; Ji, Xiangfei Green Chemistry, 2010 , vol. 12, # 3 p. 441 - 451

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Citation Number: 75

Abstract

By immobilizing a mixture of a palladium-guanidine complex and guanidine on the mesoporous cage-like material SBA-16 via a one-pot silylation, we have successfully prepared a new solid catalyst for Suzuki coupling and the aerobic oxidation of alcohols. The structure and composition of the solid catalyst were characterized with N2 sorption, XRD, TEM, FT-IR and solid state NMR. The coordination state of the palladium-guanidine ...