Asymmetric aminohydroxylation of substituted styrenes: applications in the synthesis of enantiomerically enriched arylglycinols and a diamine

SA Osborne, DD Parker

Index: O'Brien, Peter; Osborne, Simon A.; Parker, Daniel D. Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 16 p. 2519 - 2526

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Citation Number: 40

Abstract

The catalytic asymmetric aminohydroxylation of a variety of styrene derivatives and vinyl aromatics using osmium tetroxide in conjunction with alkaloid-derived ligands [(DHQ) PHAL or (DHQD) PHAL] and haloamine salts of alkyl carbamates (ethyl carbamate or-butyl carbamate) has been investigated. By observing the ef

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BOC-L-Phenylglycinol

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tert-Butyl (2-h...

Detail

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