… the van der Waals Radius of Low-Spin Ni (ii) fromMolecular Mechanics Studies and the Crystal Structures of [Ni (cis-cyclohexane-1, 3-diamine) 2] Cl2,[Ni {(R)-5, 5, 7- …

VP Munk, ST Cham, RR Fenton, RK Hocking…

Index: Munk, Vivienne P.; Cham, S. Tsuey; Fenton, Ronald R.; Hocking, Rosalie K.; Hambley, Trevor W. Australian Journal of Chemistry, 2002 , vol. 55, # 8 p. 523 - 529

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Citation Number: 6

Abstract

Abstract The structures of three bis (diamine) nickel (II) complexes, chosen to shed light on the van der Waals radius of nickel (II), are described.[Ni (cis-1, 3-chxn) 2] Cl 2 (cis-1, 3-chxn= cis-cyclohexane-1, 3-diamine) crystallizes in the monoclinic space group P2 1/n, with a 6.397 (2), b 16.463 (4), c 7.229 (2) Å, b 90.70 (2), and its structure has been refined to an R value of 0.031 on 1214F.[Ni {(R)-tmdz} 2] Cl 2· H 2 O (tmdz= 5, 5, 7-trimethyl-1, 4- ...