Chemoselective synthesis of functionalized conjugated nitroalkenes

R Ballini, R Castagnani, M Petrini

Index: Ballini, Roberto; Castagnani, Roberto; Petrini, Marino Journal of Organic Chemistry, 1992 , vol. 57, # 7 p. 2160 - 2162

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Citation Number: 98

Abstract

The utility of nitroalkenes in organic synthesis is largely due to their easy conversion into a variety of functionalities. 1 Alternatively they are powerful dienophiles in Diels-Alder reactions or readily undergo addition reactions with many different nucleophiles. The classical preparation of nitroalkenes involves the Henry condensation reaction of aldehyde or ketone with a nitroalkane followed by dehydratation of the resultant &nitro alcoholll (eq ...