Chemical Communications

Heat inhibited reactions

DM Davies, EL Stringer

Index: Davies, D. Martin; Stringer, Estelle L. Chemical Communications, 2003 , # 2 p. 224 - 225

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Abstract

Acyl transfer from p-nitrophenyl trimethylacetate to hydrogen peroxide in millimolar aqueous solutions of an amphiphilic poly (ethylene oxide)–poly (propylene oxide)–poly (ethylene oxide) triblock copolymer slows down as the temperature is raised due to partitioning of the hydrophobic ester into heat-induced micelles.

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