Abstract 2-(A) and 3-dimethylchlorosilylpyridine (B) were synthesized by reaction of the corresponding lithiopyridines with dimethyldichlorosilane at− 76 C. The products were hydrolyzed in aqueous ammonia at room temperature to give the respective disiloxanes (C and D) which are stable, colorless distillable liquids. The dimers were characterized by IR, 1 H NMR and MS. The principal by-products of the syntheses were the bis-substituted ...
[Park, Byung Il; Lee, Jung Woon; Lee, Young-A.; Hong, Jongki; Jung, Ok-Sang Bulletin of the Chemical Society of Japan, 2005 , vol. 78, # 9 p. 1624 - 1628]
