Reactions of Atomic Oxygen (3P) with Selected Alkanes

A Miyoshi, K Tsuchiya, N Yamauchi…

Index: Miyoshi, Akira; Tsuchiya, Kentaro; Yamauchi, Noboru; Matsui, Hiroyuki Journal of Physical Chemistry, 1994 , vol. 98, # 44 p. 11452 - 11458

Full Text: HTML

Citation Number: 45

Abstract

Rate constants for the reactions of atomic oxygen (3P) with selected alkanes (CZ-CS straight chain alkanes, c-CgH12, neo-CsHlz, and i-C4H10) have been determined directly by a laser photolysis-shock tube-atomic resonance absorption method at high temperatures (850-1250 K). For n-C6H14 and c-CgH12, rate constants have been also determined at lower temperatures (296-400 K) by a laser photolysis-vacuum ultraviolet laser-induced ...